Classification & declaration of Divinylbenzene for transport in tank containers

dangerous goods placard on container_web

TT Club has recently been made aware that shipper interests have been seeking to transport Divinylbenzene (DVB) from China to destinations in both Europe and United States of America, while misdeclaring the commodity as Class 9, UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Divinylbenzene). 

In the light of serious incidents, the IMDG Code was amended to include subdivision Class 4.1 for polymerizing substances with new UN numbers:


While Divinylbenzene (or related trade names, which may include Diethenylbenzene or Vinylstyrene) is not specifically named in the Dangerous Goods regulations, it is to be classified under one of these two numbers. 

It is understood that the shipper interests may be seeking to book this commodity using temperature controlled tank containers (which would generally be considered inconsistent with Class 9 in any event). The booking enquiry may be made with NVOC tank container operators or with a tank container lessors.

DVB is a liquid chemical that is prone to polymerization (a form of self-reaction). Products with a polymerization risk generally use chemical inhibitors to prevent self-reaction taking place. Such chemical inhibitors are effective for a limited period of time at a maximum temperature of about 27°C, assuming that a critical oxygen saturation is maintained. As a result, the current mandatory regulations require temperature control to ensure the cargo remains sufficiently stabilised.

Freight forwarders, logistics operators, tank container operators and lessors, NVOCs and liner carriers are urged to be alert and to take necessary action to ensure that commodities being presented for transport are correctly declared and documented for safe carriage. 

Further reading

If you would like further information, or have any comments, please email us, or take this opportunity to forward to any others who you may feel would be interested.

Peregrine Storrs-Fox
Risk Management Director

Peregrine Storrs-Fox

Risk Management Director